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Porous Carbon Adsorbent from Humin Derived from Thai Leonardite for Methylene Blue Dye Adsorption

Porous Carbon Adsorbent From Humin Derived From Thai Leonardite for Methylene Blue Dye Adsorption

Original Research ArticleFeb 11, 2019Vol. 19 No. 1 (2019)

Abstract

Leonardite is by-product from lignite mine found in northern Thailand. Leonardite is generally known as natural source of humic substances. Humic substances can be divided into three major fractions, i.e. humin, humic acids and fulvic acids. These fractions can be extracted by using solution adjusted to different acid alkaline (pH levels). Humin is a major product that can be extracted from Thai leonardite and it is over 80% yield of product. The morphology of humin is non-conductive bulk material with few porous structures. It can be used as adsorbent for dye adsorption or heavy metal and used as catalyst supporter. The synthesis of porous carbon from humin via carbonization process was investigated in this research. Humin was carbonized at different temperatures and characterized by SEM, FTIR, UV-Vis and BET. Porous carbon from humin was used in methylene blue dye adsorption. The result indicates that the particle size of humin was decreased with well-dispersed and non-agglomerate humin was observed in higher carbonization temperature. The adsorption capacity of humin was increased with increasing of temperature up to 700ºC and decreased at 900ºC according to surface area and porosity results. Although the carbon content of humin was increased at higher temperature, the function group used as adsorbent was decomposed.

 

Keywords: leonardite; humic substance; humin and carbon absorbent



Corresponding author: E-mail: apiluck.ei@kmitl.ac.th

How to Cite

Sayjumpa, J. ., Jomhataikool, B. ., Faungnawakij, K. ., Kuboon, S. ., Kraithong, W. ., Fuji, M. ., & Eiad-ua*, A. . (2019). Porous Carbon Adsorbent from Humin Derived from Thai Leonardite for Methylene Blue Dye Adsorption. CURRENT APPLIED SCIENCE AND TECHNOLOGY, 1-8.

References

  • Metivier-Pignon, H., Faur-Brasquet, C. and Cloirec, P.L., 2003. Adsorption of dyes onto activated carbon cloths: approach of adsorption mechanisms and coupling of ACC with ultra filtration to treat coloured wastewaters. Journal of Separation and Purification Technology, 31, 3–11.
  • Ghodbane, H., Hamdaoui, O., 2009. Intensification of sonochemical decolorization of anthraquinonic dye acid blue 25 using carbon tetrachloride. Journal of Ultrasonics Sonochemistry, 16(4), 455-461.
  • Rafatullah, M., Sulaiman, O., Hashim, R. and Ahmad, A., 2010. Adsorption of methylene blue on low-cost adsorbents: a review. Journal of Hazardous Materials, 177, 70–80.
  • Dabrowski, A., 2001. Adsorption from theory to practice. Journal of Advances in Colloid and Interface Science, 93, 135–224.
  • Gayatri1, S. L. and Ahmaruzzaman, Md., 2010. Adsorption technique for the removal of phenolic compounds from wastewater using low-cost natural adsorbents. Journal of Science & Technology, 5(2), 157-166.

Author Information

Jutaporn Sayjumpa

College of Nanotechnology, King Mongkut's Institute of Technology Ladkrabang, Bangkok, Thailand

Buntita Jomhataikool

College of Nanotechnology, King Mongkut's Institute of Technology Ladkrabang, Bangkok, Thailand

Kajornsak Faungnawakij

National Nanotechnology Center, National Science and Technology Development Agency, Pathumthani, Thailand

Sanchai Kuboon

National Nanotechnology Center, National Science and Technology Development Agency, Pathumthani, Thailand

Wasawat Kraithong

National Nanotechnology Center, National Science and Technology Development Agency, Pathumthani, Thailand

Masayoshi Fuji

Advanced Ceramic Research Center, Nagoya Institute of Technology, Tajimi, Japan

Apiluck Eiad-ua*

College of Nanotechnology, King Mongkut's Institute of Technology Ladkrabang, Bangkok, Thailand

About this Article

Journal

Vol. 19 No. 1 (2019)

Type of Manuscript

Original Research Article

Keywords

leonardite; humic substance; humin and carbon absorbent

Published

11 February 2019