/
/
/
Modeling for Conversion of Two-phase Esterification for Biodiesel Production

Modeling for Conversion of Two-Phase Esterification for Biodiesel Production

Regular PaperMar 30, 2018Vol. 13 No. 1 (2013)

Abstract

The conversion of two-phase esterification was performed with the employment of two approaches whereby in the first approach, pseudo-homogeneous phase was assumed and deviation from the experimental data was noticeably observed; and to overcome the drawback, in the second approach, vapor-liquid equilibrium (VLE) was accounted for using ASPEN PLUS and the reaction was allowed to occur in small-time steps using the fatty acid catalyzed kinetics model prior to subsequent VLE calculation. It is assumed in the second approach that transfer between the phases would be faster than the reaction in the separate phases. The outcomes of the second approach show good agreement between the calculated conversion and experimental esterification data in the presence of two phases.

Keyword: Esterification, Biodiesel, Conversion Modeling, Vapor-Liquid equilibrium

Email: kptanawa@kmitl.ac.th

How to Cite

Pinnarat*, T. . (2018). Modeling for Conversion of Two-phase Esterification for Biodiesel Production. CURRENT APPLIED SCIENCE AND TECHNOLOGY, 33-37.

References

  • [1] S. Changi, T. Pinnarat, and P.E. Savage, “Modeling Hydrolysis and Esterification Kinetics for Biofuel Processes,” Industrial & Engineering Chemistry Research, 2011.
  • [2] T. Pinnarat and P.E. Savage, “Noncatalytic esterification of oleic acid in ethanol,” The Journal of Supercritical Fluids, vol. 53, 2010, pp. 53–59.
  • [3] E.C. Carlson, “Don't gamble with physical properties for simulations,” Chemical Engineering Progress, vol. 92, 1996, pp. 35–46.

Author Information

Tanawan Pinnarat*

Chemical Engineering Department, Faculty of Engineering, King Mongkut’s Institute of Technology, Bangkok, Thailand

About this Article

Journal

Vol. 13 No. 1 (2013)

Type of Manuscript

Regular Paper

Keywords

Esterification, Biodiesel, Conversion Modeling, Vapor-Liquid equilibrium

Published

30 March 2018